发布网友 发布时间:2024-09-06 16:03
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热心网友 时间:2024-12-04 23:46
虽然醋是弱酸,pH不至于5~6吧! Ka = [H+][CH3COO-] / [CH3COOH] 5% 醋酸开稀 10 倍 = 0.5% 醋酸 100% 醋酸 = 17.48 M 0.5% 醋酸(容积百分比) = 0.0874 M Ka(醋酸) = 1.7 * 10^-5 per mol per dm^3 1.7 * 10^-5 = [H+]^2 / 0.0874 [H+]^2 = 1.4858 * 10^-6 [H+] = 1.2189 * 10^-3 pH(5% 醋酸开稀 10 倍) = - log(1.2189 * 10^-3) = 2.91 假设醋 = 5% 醋酸 5% 醋 = 0.25% 醋酸 5% 醋开稀 10 倍 = 0.025% 醋酸 100% 醋酸 = 17.48 M 0.025% 醋酸(容积百分比) = 0.00437 M Ka(醋酸) = 1.7 * 10^-5 per mol per dm^3 1.7 * 10^-5 = [H+]^2 / 0.00437 [H+]^2 = 7.429 * 10^-8 [H+] = 2.726 * 10^-4 pH(5% 醋开稀 10 倍) = - log(2.726 * 10^-4) pH(5% 醋开稀 10 倍) = 3.56 假设醋 = 3% 醋酸 5% 醋 = 0.15% 醋酸 5% 醋开稀 10 倍 = 0.015% 醋酸 100% 醋酸 = 17.48 M 0.025% 醋酸(容积百分比) = 0.002622 M Ka(醋酸) = 1.7 * 10^-5 per mol per dm^3 1.7 * 10^-5 = [H+]^2 / 0.002622 [H+]^2 = 4.457 * 10^-8 [H+] = 2.111 * 10^-4 pH(5% 醋开稀 10 倍) = - log(1.2189 * 10^-3) pH(5% 醋开稀 10 倍) = 3.67 由于醋中还有少量的酒石酸、柠檬酸等, 所以pH值比算出的低(更酸)。 希望解答到你 ^^